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  • Publicada en Nature Materials investigación coliderada por Mariano Campoy sobre la obtención de paneles solares que permitan un mayor rendimiento energético.

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Publicada en Nature Materials investigación coliderada por Mariano Campoy sobre la obtención de paneles solares que permitan un mayor rendimiento energético.

Se ha publicado en Nature Materials un trabajo de Mariano Campoy del ICMAB-CSIC y Jenny Nelson del Imperial College en el que se concluye que los polímeros con estructura molecular sin curvatura son mejores para la obtención de paneles solares más efectivos. Los materiales resultantes consiguen pasar del  4%  o el 5% de eficiencia al 8,5% 

icmab
May 17, 2016

Exploring the origin of high optical absorption in conjugated polymers.
Vezie, M., Few, S., Meager, I. et al.  Nature Mater 15, 746–753 (2016). https://doi.org/10.1038/nmat4645

The specific optical absorption of an organic semiconductor is critical to the performance of organic optoelectronic devices. For example, higher light-harvesting efficiency can lead to higher photocurrent in solar cells that are limited by sub-optimal electrical transport. Here, we compare over 40 conjugated polymers, and find that many different chemical structures share an apparent maximum in their extinction coefficients. However, a diketopyrrolopyrrole-thienothiophene copolymer shows remarkably high optical absorption at relatively low photon energies. By investigating its backbone structure and conformation with measurements and quantum chemical calculations, we find that the high optical absorption can be explained by the high persistence length of the polymer. Accordingly, we demonstrate high absorption in other polymers with high theoretical persistence length. Visible light harvesting may be enhanced in other conjugated polymers through judicious design of the structure.



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